Transmetalation reaction of dimethylzinc and (bis(2-pyridyl)methyl)lithium

被引：18

作者：

Gornitzka, H

Hemmert, C

Bertrand, G

Pfeiffer, M

Stalke, D

机构：

[1] CNRS, Chim Coordinat Lab, F-31077 Toulouse, France

[2] Univ Wurzburg, Inst Anorgan Chem, D-97074 Wurzburg, Germany

来源：

ORGANOMETALLICS | 2000年 / 19卷 / 02期

关键词：

D O I：

10.1021/om990815k

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The unexpected transmetalation reaction between the (bis(2-pyridyl)methyl)lithium compound [(THF)(2)LiPy2CH] (1) and dimethylzinc produces the novel dimer [MeZnC(H)Py-2](2) (2), in which dimerization occurs via mutual ring N-->Zn chelation between two monomers which contain. Zn-C bonds. White all known (2-pyridyl)methyl anions are C(sp(2))-centered planar ligands, structural evidence in 2 shows that the central carbon, atom is partially sp(3)-hybridized.

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页码：112 / 114

页数：3

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