Highly efficient metal-free organic dyes for dye-sensitized solar cells

被引:141
作者
Horiuchi, T
Miura, H
Uchida, S
机构
[1] Mitsubishi Paper Mills Co Ltd, Technol Res Lab, Corp Res Ctr, Tsukuba, Ibaraki 3004247, Japan
[2] Tohoku Univ, IMRAM, Aoba Ku, Sendai, Miyagi 9808577, Japan
关键词
dye-sensitized solar cell; metal-free organic dyes; J-aggregate;
D O I
10.1016/j.jphotochem.2003.12.018
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A solar-to-electric conversion efficiency of 5.1% is achieved with this new dye, compared to 5.8% for N3 dye under the same experimental conditions. Although these indoline dyes are slightly less efficient than N3 dye [cis-Ru(II)(2,2'-bipyridil-4,4'-dicarboxilic acid) (NCS)], the cost would be expected much lower because it does not contain any noble, rare metals in the structure and also it is easy to prepare specially for the mass production. Furthermore, indoline dyes are shown to be highly stable to photoredox processes by cyclic voltammogram. (C) 2004 Elsevier B.V. All rights reserved.
引用
收藏
页码:29 / 32
页数:4
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