Fluorescence and excitation spectra of Ag4 in an argon matrix

被引:119
作者
Félix, C
Sieber, C
Harbich, W
Buttet, J
Rabin, I
Schulze, W
Ertl, G
机构
[1] Ecole Polytech Fed Lausanne, Inst Phys Expt, CH-1015 Lausanne, Switzerland
[2] Max Planck Gesell, Fritz Haber Inst, D-14195 Berlin, Germany
关键词
D O I
10.1016/S0009-2614(99)01034-9
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
We report the fluorescence and excitation spectra of size selected Ag, deposited in an argon matrix. The main fluorescence peak for Ag, is observed at 458 nm. The excitation spectrum for this emission is in good agreement with recent theoretical calculations and photodepletion experiments. (C) 1999 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:105 / 109
页数:5
相关论文
共 17 条
[1]   An accurate relativistic effective core potential for excited states of Ag atom:: An application for studying the absorption spectra of Agn and Agn+ clusters [J].
Bonacic-Koutecky, V ;
Pittner, J ;
Boiron, M ;
Fantucci, P .
JOURNAL OF CHEMICAL PHYSICS, 1999, 110 (08) :3876-3886
[2]   METAL CLUSTER ION PHOTOFRAGMENTATION [J].
BRUCAT, PJ ;
ZHENG, LS ;
PETTIETTE, CL ;
YANG, S ;
SMALLEY, RE .
JOURNAL OF CHEMICAL PHYSICS, 1986, 84 (06) :3078-3088
[3]   OPTICAL SPECTROSCOPY OF AG7, AG-9+, AND AG9 - A TEST OF THE PHOTODEPLETION METHOD [J].
COLLINGS, BA ;
ATHANASSENAS, K ;
RAYNER, DM ;
HACKETT, PA .
CHEMICAL PHYSICS LETTERS, 1994, 227 (4-5) :490-495
[4]   THE PHYSICS OF SIMPLE METAL-CLUSTERS - EXPERIMENTAL ASPECTS AND SIMPLE-MODELS [J].
DEHEER, WA .
REVIEWS OF MODERN PHYSICS, 1993, 65 (03) :611-676
[5]  
DUNCAN MA, 1993, ADV METAL SEMICONDUC, V1, P123
[6]   OPTICAL-RESPONSE OF AG2, AG3, AU2, AND AU3 IN ARGON MATRICES [J].
FEDRIGO, S ;
HARBICH, W ;
BUTTET, J .
JOURNAL OF CHEMICAL PHYSICS, 1993, 99 (08) :5712-5717
[7]   Soft landing and fragmentation of small clusters deposited in noble-gas films [J].
Fedrigo, S ;
Harbich, W ;
Buttet, J .
PHYSICAL REVIEW B, 1998, 58 (11) :7428-7433
[8]   DEPOSITION OF MASS SELECTED SILVER CLUSTERS IN RARE-GAS MATRICES [J].
HARBICH, W ;
FEDRIGO, S ;
MEYER, F ;
LINDSAY, DM ;
LIGNIERES, J ;
RIVOAL, JC ;
KREISLE, D .
JOURNAL OF CHEMICAL PHYSICS, 1990, 93 (12) :8535-8543
[9]  
HARBICH W, 1993, Z PHYS D, V26, P1
[10]  
KONIG L, 1996, THESIS TU BERLIN