Axially chiral directly β,β-linked bisporphyrins:: Synthesis and stereostructure

被引：55

作者：

Bringmann, Gerhard ^{[1
]}

Ruedenauer, Stefan ^{[1
]}

Goetz, Daniel C. G. ^{[1
]}

Gulder, Tobias A. M. ^{[1
]}

Reichert, Matthias ^{[1
]}

机构：

[1] Univ Wurzburg, Inst Organ Chem, D-97074 Wurzburg, Germany

来源：

ORGANIC LETTERS | 2006年 / 8卷 / 21期

关键词：

SEMIEMPIRICAL METHODS; LINKED DIPORPHYRIN; PORPHYRIN DIMERS; DENSITY; CATALYSTS; RECOGNITION; CYCLIZATION; ALDEHYDES; EXCHANGE; LIGANDS;

D O I：

10.1021/ol061812o

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A novel type of "superbiaryl", the first porphyrin dimers with an intrinsically chiral structure, has been prepared. The atropo-enantiomers were configurationally assigned by HPLC-CD combined with quantum chemical CD calculations.

引用

页码：4743 / 4746

页数：4

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