Magnetic characterization of λ-MnO2 and Li2Mn2O4 prepared by electrochemical cycling of LiMn2O4

被引：40

作者：

Jang, YI

Huang, B

Chou, FC

Sadoway, DR

Chiang, YM ^{[1
]}

机构：

[1] MIT, Dept Mat Sci & Engn, Cambridge, MA 02139 USA

[2] MIT, Ctr Mat Sci & Engn, Cambridge, MA 02139 USA

来源：

JOURNAL OF APPLIED PHYSICS | 2000年 / 87卷 / 10期

关键词：

D O I：

10.1063/1.372997

中图分类号：

O59 [应用物理学];

学科分类号：

摘要：

Magnetic characterization has been performed on the cubic phases lambda-Li0.07Mn2O4, Li0.98Mn2O4, and the tetragonal phase Li1.82Mn2O4, prepared by electrochemical cycling of a single starting LiMn2O4 spinel. The magnitude of the negative Weiss constant increases with x in LixMn2O4, indicating that antiferromagnetic interactions increase in strength as the Mn4+ concentration decreases. Spin-glass behavior is observed in all three materials, as previously seen in nearly stoichiometric LiMn2O4 [Jang et al., Appl. Phys. Lett. 74, 2504 (1999)]. A short-range antiferromagnetic correlation is observed in Li2Mn2O4 at temperatures below the paramagnetic temperature regime, which is ascribed to collective Jahn-Teller distortion causing a two-dimensional nearest-Mn-neighbors interaction. (C) 2000 American Institute of Physics. [S0021-8979(00)05910-7].

引用

页码：7382 / 7388

页数：7

共 36 条

[1]

Binder K., 1986, REV MOD PHYS, V58, P802

[2] FERROMAGNETISM AND FERRIMAGNETISM OF OXYGEN SPINELS CONTAINING TETRAVALENT MANGANESE [J].