Synthetic water-oxidation catalysts for artificial photosynthetic water oxidation

被引：647

作者：

Ruttinger, W ^{[1
]}

Dismukes, GC ^{[1
]}

机构：

[1] PRINCETON UNIV, HOYT LAB, DEPT CHEM, PRINCETON, NJ 08544 USA

来源：

CHEMICAL REVIEWS | 1997年 / 97卷 / 01期

关键词：

D O I：

10.1021/cr950201z

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

This paper focuses on homogeneous catalysts for the oxidation of water. It provides an overview of the photosynthetic water-oxidizing complex (WOC) and its functionality, followed by analysis of the thermodynamic and kinetic constraints for water-oxidation that have to be overcome by any catalyst. Since manganese is the metal that performs this reaction in the WOC, manganese catalysts are discussed, followed by ruthenium. Finally, the principles of reactivity learned from theory and existing models that will guide toward synthesis of better catalysts in the future are summarized.

引用

页码：1 / 24

页数：24

共 136 条

[1]

Abragam A., 1970, ELECT PARAMAGNETIC R, P175

[2] THE PHOTOLYSIS OF COORDINATED WATER IN [MN(SALTM)(H2O)]2(CIO4)2 [SALTM = N,N'-PROPYLENEBIS(SALICYLIDENEAMINATO)] [J].

ASHMAWY, FM ;

MCAULIFFE, CA ;

PARISH, RV ;

TAMES, J .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1984, (01) :14-16

[3] WATER PHOTOLYSIS .1. THE PHOTOLYSIS OF COORDINATED WATER IN [(MNL-(H2O))2][CLO4]2 (L = DIANION OF TETRADENTATE O2N2-DONOR SCHIFF-BASES) - A MODEL FOR THE MANGANESE SITE IN PHOTOSYSTEM-II OF GREEN PLANT PHOTOSYNTHESIS [J].

ASHMAWY, FM ;

MCAULIFFE, CA ;

PARISH, RV ;

TAMES, J .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1985, (07) :1391-1397

[4] CRYSTALLOGRAPHIC CHARACTERIZATION OF A POSSIBLE MODEL FOR PHOTOSYSTEM-II [J].

AURANGZEB, N ;

HULME, CE ;

MCAULIFFE, CA ;

PRITCHARD, RG ;

WATKINSON, M ;

BERMEJO, MR ;

GARCIADEIBE, A ;

REY, M ;

SANMARTIN, J ;

SOUSA, A .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1994, (09) :1153-1155

[5]

BABCOCK GT, 1976, FEBS LETT, V61, P286

[6] WATER OXIDATION IN PHOTOSYSTEM .2. FROM RADICAL CHEMISTRY TO MULTIELECTRON CHEMISTRY [J].

BABCOCK, GT ;

BARRY, BA ;

DEBUS, RJ ;

HOGANSON, CW ;

ATAMIAN, M ;

MCINTOSH, L ;

SITHOLE, I ;

YOCUM, CF .

BIOCHEMISTRY, 1989, 28 (25) :9557-9565

[7] THE EFFECT OF PROTONATION ON [MN(IV)(MU(2)-O)](2) COMPLEXES [J].

BALDWIN, MJ ;

GELASCO, A ;

PECORARO, VL .

PHOTOSYNTHESIS RESEARCH, 1993, 38 (03) :303-308

[8] MODELING THE PHOTOSYNTHETIC WATER OXIDATION CENTER - PREPARATION AND PHYSICAL-PROPERTIES OF A TETRANUCLEAR OXIDE BRIDGED MN COMPLEX CORRESPONDING TO THE NATIVE S-2 STATE [J].

BASHKIN, JS ;

CHANG, HR ;

STREIB, WE ;

HUFFMAN, JC ;

HENDRICKSON, DN ;

CHRISTOU, G .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1987, 109 (21) :6502-6504

[9] MECHANISM OF PHOTOINHIBITION OF PHOTOSYNTHETIC WATER OXIDATION BY CL- DEPLETION AND F- SUBSTITUTION - OXIDATION OF A PROTEIN RESIDUE [J].

BAUMGARTEN, M ;

PHILO, JS ;

DISMUKES, GC .

BIOCHEMISTRY, 1990, 29 (48) :10814-10822

[10] TOWARDS ARTIFICIAL PHOTOSYNTHESIS - EXPERIMENTS WITH SILVER ZEOLITES .2. [J].

BEER, R ;

CALZAFERRI, G ;

LI, JW ;

WALDECK, B .

COORDINATION CHEMISTRY REVIEWS, 1991, 111 :193-200

← 1 2 3 4 5 6 7 8 9 10 →