Long-lived nuclear spin states in high-field solution NMR

被引:270
作者
Carravetta, M [1 ]
Levitt, MH [1 ]
机构
[1] Univ Southampton, Sch Chem, Southampton SO17 1BJ, Hants, England
关键词
D O I
10.1021/ja0490931
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Nuclear spin order may be stored in a liquid for a much longer time than the longitudinal relaxation time T1, by using rf fields to isolate states of different symmetry. The method is demonstrated on a sample containing AX spin systems. Copyright © 2003 American Chemical Society.
引用
收藏
页码:6228 / 6229
页数:2
相关论文
共 9 条
[1]   PARA-HYDROGEN AND SYNTHESIS ALLOW DRAMATICALLY ENHANCED NUCLEAR ALIGNMENT [J].
BOWERS, CR ;
WEITEKAMP, DP .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1987, 109 (18) :5541-5542
[2]   Beyond the T1 limit:: Singlet nuclear spin states in low magnetic fields -: art. no. 153003 [J].
Carravetta, M ;
Johannessen, OG ;
Levitt, MH .
PHYSICAL REVIEW LETTERS, 2004, 92 (15) :153003-1
[3]   Applications of the parahydrogen phenomenon: A chemical perspective [J].
Duckett, SB ;
Sleigh, CJ .
PROGRESS IN NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY, 1999, 34 (01) :71-92
[4]   COHERENT AVERAGING EFFECTS IN MAGNETIC RESONANCE [J].
HAEBERLEN, U ;
WAUGH, JS .
PHYSICAL REVIEW, 1968, 175 (02) :453-+
[5]   Parahydrogen induced polarization [J].
Natterer, J ;
Bargon, J .
PROGRESS IN NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY, 1997, 31 :293-315
[6]   AN IMPROVED SEQUENCE FOR BROAD-BAND DECOUPLING - WALTZ-16 [J].
SHAKA, AJ ;
KEELER, J ;
FRENKIEL, T ;
FREEMAN, R .
JOURNAL OF MAGNETIC RESONANCE, 1983, 52 (02) :335-338
[7]   ITERATIVE SCHEMES FOR BILINEAR OPERATORS - APPLICATION TO SPIN DECOUPLING [J].
SHAKA, AJ ;
LEE, CJ ;
PINES, A .
JOURNAL OF MAGNETIC RESONANCE, 1988, 77 (02) :274-293
[8]   Experimental realization of noiseless subsystems for quantum information processing [J].
Viola, L ;
Fortunato, EM ;
Pravia, MA ;
Knill, E ;
Laflamme, R ;
Cory, DG .
SCIENCE, 2001, 293 (5537) :2059-2063
[9]   Stabilizing quantum information [J].
Zanardi, P .
PHYSICAL REVIEW A, 2001, 63 (01) :012301-012301