Molecular design of photocurable liquid biodegradable copolymers. 2. Synthesis of coumarin-derivatized oligo(methacrylate)s and photocuring

被引：35

作者：

Matsuda, T ^{[1
]}

Mizutani, M ^{[1
]}

机构：

[1] Natl Cardiovasc Ctr, Res Inst, Dept Bioengn, Suita, Osaka 5658565, Japan

来源：

MACROMOLECULES | 2000年 / 33卷 / 03期

关键词：

D O I：

10.1021/ma991405a

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Photocurable, biodegradable liquid copolymers, which undergo liquid-to-gel transformation upon ultraviolet (UV) light irradiation, may find versatile biomaterial applications. A multifunctionally derivatized liquid prepolymer that is oligo(2-hydroxyl methacrylate) grafted with oligo(epsilon-caprolactone) and subsequently end-capped with a photodimerizable group, coumarin, at the terminal ends of the side chains, was prepared. UV irradiation produced a cross-linked solid.

引用

页码：791 / 794

页数：4

共 11 条

[1] DEGRADABLE POLYMERS FOR THE FUTURE [J].

ALBERTSSON, AC ;

KARLSSON, S .

ACTA POLYMERICA, 1995, 46 (02) :114-123

[2]

BEZWADA RS, 1995, Patent No. 5653992

[3]

Kito H, 1993, ASAIO J, V39, pM506

[4]

MATSUDA T, IN PRESS MACROMOLECU

[5]

Moghaddam M J, 1991, ASAIO Trans, V37, pM437

[6] MOLECULAR DESIGN OF 3-DIMENSIONAL ARTIFICIAL EXTRACELLULAR-MATRIX - PHOTOSENSITIVE POLYMERS CONTAINING CELL ADHESIVE PEPTIDE [J].

MOGHADDAM, MJ ;

MATSUDA, T .

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1993, 31 (06) :1589-1597

[7]

Piskin E., 1994, J BIOMAT SCI-POLYM E, V6, P775

[8]

SCOPELIANOS AG, 1994, Patent No. 5599852

[9]

SCOPELIANOS AG, 1996, Patent No. 5728752

[10]

SCOPELIANOS AG, 1996, Patent No. 5824333

← 1 2 →