Solvent templated synthesis of metal-organic frameworks:: structural characterisation and properties of the 3D network isomers {[Mn(dcbp)]•1/2DMF}n and {[Mn(dcbp)]•2H2O}n

被引：114

作者：

Tynan, E ^{[1
]}

Jensen, P ^{[1
]}

Kruger, PE ^{[1
]}

Lees, AC ^{[1
]}

机构：

[1] Univ Dublin Trinity Coll, Dept Chem, Dublin 2, Ireland

来源：

CHEMICAL COMMUNICATIONS | 2004年 / 07期

关键词：

D O I：

10.1039/b315483a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The identity of the metal-organic framework formed by Mn(II) and 4,4'-dicarboxy-2,2'-bipyridine (H(2)dcbp) depends upon the predominant solvent employed in the synthesis and yields the robust network isomers [[Mn(dcbp)].1/2 DMF}(n), 1, and {[Mn(dcbp)].2H(2)O}(n), 2, which possess vastly different physical properties: 1 irretrievably binds DMF, whereas 2 reversibly binds water whilst retaining crystallinity.

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页码：776 / 777

页数：2

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