Greatly attenuated reactivity of nitrile-derived carbon-centered radicals toward oxygen

被引：57

作者：

Font-Sanchis, E ^{[1
]}

Aliaga, C ^{[1
]}

Focsaneanu, KS ^{[1
]}

Scaiano, JC ^{[1
]}

机构：

[1] Univ Ottawa, Dept Chem, Ottawa, ON K1N 6N5, Canada

来源：

CHEMICAL COMMUNICATIONS | 2002年 / 15期

关键词：

D O I：

10.1039/b203158b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Several cyanoalkyl radicals are reported to be unreactive toward oxygen; spin delocalization on nitrogen is proposed to be the most important factor to explain this unusual behaviour.

引用

页码：1576 / 1577

页数：2

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