A new route to heterobimetallic C3 complexes via CC metatheses of 1,3-diynyl ligands:: Synthesis and structure of (η5-C5Me5)Re(NO)(PPh3)(CCC)W(O-t-Bu)3

被引：34

作者：

Dembinski, R

Szafert, S

Haquette, P

Lis, T

Gladysz, JA ^{[1
]}

机构：

[1] Univ Utah, Dept Chem, Salt Lake City, UT 84112 USA

[2] Wroclaw B Beirut Univ, Dept Chem, PL-50383 Wroclaw, Poland

[3] Univ Erlangen Nurnberg, Inst Organ Chem, D-91054 Erlangen, Germany

来源：

ORGANOMETALLICS | 1999年 / 18卷 / 26期

关键词：

D O I：

10.1021/om990766b

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reactions of (eta(5)-C5Me5)Re(NO)(PPh3)(C=CC=CR) (R = Me, H) and (t-BuO)(3)W=W(O-t-Bu)(3) give (t-BuO)(3)W=CR and the title complex (79-76%), which crystallizes from toluene as a solvated tert-butoxy-bridged dimer. The NMR, IR, and crystallographic properties establish dominant Re-C=C-C=W as opposed to Re+=C=C=C=W- character.

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页码：5438 / 5440

页数：3

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