Ruthenium induced C-N bond activation of an N-heterocyclic carbene: Isolation of C- and N-bound tautomers

被引：162

作者：

Burling, Suzanne ^{[1
]}

Mahon, Mary F. ^{[1
]}

Powell, Rachael E. ^{[1
]}

Whittlesey, Michael K. ^{[1
]}

Williams, Jonathan M. J. ^{[1
]}

机构：

[1] Univ Bath, Dept Chem, Bath BA2 7AY, Avon, England

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2006年 / 128卷 / 42期

基金：

英国工程与自然科学研究理事会;

关键词：

D O I：

10.1021/ja065582k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

C-N bond activation of the N-heterocyclic carbene 1,3-diisopropyl-4,5-dimethylimidazol-2-ylidene occurs with Ru(PPh3)3(CO)HCl to give the C-2 bound 1-isopropyl-4,5-dimethylimidazol-2-ylidene complex Ru(C-IiPrHMe2)(PPh3)2(CO)HCl via loss of propene. In the presence of free carbene, this undergoes tautomerism to the corresponding imidazole compound Ru(N-IiPrHMe2)(PPh3)2(CO)HCl. Copyright © 2006 American Chemical Society.

引用

页码：13702 / 13703

页数：2

共 26 条

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