Influence of the interplay of crystallization and chain stretching on micellar morphologies:: Solution self-assembly of coil-crystalline poly(isoprene-block-ferrocenylsilane)

被引：192

作者：

Cao, L ^{[1
]}

Manners, I ^{[1
]}

Winnik, MA ^{[1
]}

机构：

[1] Univ Toronto, Dept Chem, Toronto, ON M5S 3H6, Canada

来源：

MACROMOLECULES | 2002年 / 35卷 / 22期

关键词：

D O I：

10.1021/ma021068x

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The influence of the interplay of crystallization and chain stretching on micellar morphologies was discussed. A change in block length for coil-crystalline poly(isoprene-block-ferrocenyldimethylsilane) (PI-b-PFS) leads to a change in micelle structure. Results showed that the use of crystalline blocks represented a potentially powerful approach to systematically control micellar morphology.

引用

页码：8258 / 8260

页数：3

共 27 条

[1] 1998 E.W.R. Steacie Award Lecture Asymmetric amphiphilic block copolymers in solution: a morphological wonderland [J].