Octakis(3-propylammonium) octadecaiodopentaplumbate(II): a new layered stucture based on layered perovskites

被引：8

作者：

Billing, David G. ^{[1
]}

Lemmerer, Andreas ^{[1
]}

机构：

[1] Univ Witwatersrand, Sch Chem, ZA-2050 Wits, South Africa

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY | 2006年 / 62卷

关键词：

D O I：

10.1107/S0108270106014417

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The title compound, (C3H10N)(8)[Pb5I18], crystallizes as an inorganic-organic hybrid. As such, the structure consists of two-dimensional sheets of corner- and face-sharing [PbI6](4-) octahedra, separated by layers of 3-propylammonium cations, which hydrogen bond to the I atoms. The asymmetric unit contains six independent Pb atoms; four are on general positions and the other two are on special positions, viz. a centre of inversion and a twofold axis. The inorganic sheets show a never before seen motif.

引用

页码：M238 / M240

页数：3

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