Ruthenium-catalyzed propargylation of aromatic compounds with propargylic alcohols

被引：186

作者：

Nishibayashi, Y

Yoshikawa, M

Inada, Y

Hidai, M ^{[1
]}

Uemura, S

机构：

[1] Sci Univ Tokyo, Dept Mat Sci & Technol, Noda, Chiba 2788510, Japan

[2] Kyoto Univ, Dept Energy & Hydrocarbon Chem, Sakyo Ku, Kyoto 6068501, Japan

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2002年 / 124卷 / 40期

基金：

日本科学技术振兴机构;

关键词：

D O I：

10.1021/ja027023t

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A novel ruthenium-catalyzed propargylation of aromatic compounds with propargylic alcohols has been found to afford the corresponding propargylated aromatic products in good yields with complete regioselectivity. The catalytic reaction provides a potential usefulness for practical application in organic synthesis, because the selective propargylation of aromatic compounds with an aromatic C-H bond cleavage is generally difficult. Copyright © 2002 American Chemical Society.

引用

页码：11846 / 11847

页数：2

共 25 条

[1] A THEORETICAL-STUDY OF THE MEYER-SCHUSTER REACTION-MECHANISM - MINIMUM-ENERGY PROFILE AND PROPERTIES OF TRANSITION-STATE STRUCTURE [J].