Catalytic enantioselective intermolecular [2+2+2] cycloaddition of an alkene and two alkynes

被引：44

作者：

Ikeda, S ^{[1
]}

Kondo, H ^{[1
]}

Arii, T ^{[1
]}

Odashima, K ^{[1
]}

机构：

[1] Nagoya City Univ, Grad Sch Pharmaceut Sci, Mizuho Ku, Nagoya, Aichi 4678603, Japan

来源：

CHEMICAL COMMUNICATIONS | 2002年 / 20期

关键词：

D O I：

10.1039/b208313b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A catalytic enantioselective intermolecular [2 + 2 + 2] cycloaddition of one molecule of alkene (enone) and two molecules of alkyne was developed in the presence of a nickel complex modified by chiral monodentate oxazoline ligands, which have not previously been used as chiral ligands for transition metals in asymmetric catalysts, and an aluminium phenoxide.

引用

页码：2422 / 2423

页数：2

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