A new kinetic model for the photopolymerization shrinkage-strain of dental composites and resin-monomers

Objectives. The aim of the study was to develop a new kinetic model for the shrinkage-strain rates of dental resin composites. The effect of filler content on the shrinkage-strain kinetics and degree of conversion of dental composites was also investigated. Methods. A resin matrix containing 65 wt.% Bis-GMA and 35 wt.% TEGDMA was prepared. 0.5 wt.% camphorquinone and 0.5 wt.% dimethyl aminoethyl methacrylate were dissolved in the resin as photo-initiator system. Silanized glass fillers were added in different percentages to the resin-monomers. The shrinkage-strain of the specimens photopolymerized at circa 550 mW/cm(2) was measured using the bonded-disc technique at 23, 37 and 45 degrees C for the matrix monomers and 23 degrees C for the composites. Initial shrinkage-strain rates were obtained by numerical differentiation of shrinkage-strain data with respect to time. Degree-of-conversion of the composites containing different filler contents was measured using FTIR spectroscopy. Results. A new kinetic model was developed for the shrinkage-strain rate using the autocatalytic model of Kamal [Kamal MR, Sourour S. Kinetic and thermal characterization of thermoset cure. Polym Eng Sci 1973;13(1):59-64], which is used to describe the reaction kinetics of thermoset resins. The model predictions were in good agreement with the experimental data. The results also showed a linear correlation between the shrinkage-strain (and shrinkage-strain rate) and filler-volume fraction. The filler fraction did not affect the degree-of-conversion of the composites. Significance. The rate of polymerization, determined via the shrinkage, being invariant with filler-fraction, suggests that only a relatively high filler-surface area, as may be obtained with nano-fillers, will affect the network-forming kinetics of the resin matrix. (C) 2006 Academy of Dental Materials. Published by Elsevier Ltd. All rights reserved.