High-yield ruthenium-catalyzed Friedel-Crafts type allylation reactions using dicationic RuIV catalysts

被引：69

作者：

Fernandez, Ignacio

Hermatschweiler, Rene

Breher, Frank

Pregosin, Paul S. ^{[1
]}

Veiros, Luis F.

Calhorda, Maria Jose

机构：

[1] ETHZ, Inorgan Chem Lab, CH-8093 Zurich, Switzerland

[2] Univ Karlsruhe, Inst Anorgan Chem, D-76131 Karlsruhe, Germany

[3] Ctr Quim Estrutural, Inst Super Tecn, P-1049001 Lisbon, Portugal

[4] Univ Lisbon, Fac Ciencias, Dept Quim & Bioquim, P-1749016 Lisbon, Portugal

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2006年 / 45卷 / 38期

关键词：

allylations; density functional calculations; NMR spectroscopy; ruthenium; structure elucidation;

D O I：

10.1002/anie.200600447

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical Equation Presented) Unexpected linkage: The use of dicationic RuIV complexes in the Friedel-Crafts-type allylation of aromatic alcohols leads unexpectedly to the formation of a new C-C bond and not to the phenolation product (see scheme). NMR spectroscopy, diffusion data, DFT calculations, and X-ray diffraction analysis provide new insights with respect to the mechanism of this reaction. © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：6386 / 6391

页数：6

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