Preparation of bis(polyfluoroalkyl)cyclopentadienes, new highly fluorophilic ligands for fluorous biphase catalysis

被引：43

作者：

Bríza, T

Kvícala, J

Paleta, O

Cermák, J

机构：

[1] Inst Chem Technol Prague, Dept Organ Chem, Prague 16628 6, Czech Republic

[2] Acad Sci Czech Republ, Inst Chem Proc Fundamentals, Prague 16502 6, Czech Republic

来源：

TETRAHEDRON | 2002年 / 58卷 / 20期

关键词：

fluorous; fluorophilic; fluorocyclopentadiene; bis(polyfluoroalkyl)cyclopentadiene; fluoroalkyl triflate; (perfluoroalkyl)ethyl triflate;

D O I：

10.1016/S0040-4020(02)00212-0

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Bis[2-(perfluoroalkyl)ethyl]cyclopentadienes were synthesized from lithium [2- (perfluoroalkyl)ethyl]cyclopentadienides and 2-(perfluoroalkyl) ethyl triflates as mixtures of four regioisomers, structure of which was determined by H-1 and C-13 NMR spectroscopy. 2-(Perfluoroatkyl)ethyl triflates are useful fluorinated building blocks that can be employed in the synthesis of functionalised polyfluorinated substances. (C) 2002 Elsevier Science Ltd. All rights reserved.

引用

页码：3841 / 3846

页数：6

共 25 条

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