Diazadithiafulvalenes as electron donor reagents

被引：27

作者：

Koizumi, T ^{[1
]}

Bashir, N ^{[1
]}

Kennedy, AR ^{[1
]}

Murphy, JA ^{[1
]}

机构：

[1] Univ Strathclyde, Dept Pure & Appl Chem, Glasgow G1 1XL, Lanark, Scotland

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1999年 / 24期

关键词：

D O I：

10.1039/a906684e

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Diazadithiafulvalenes act as excellent electron donors to arenediazonium salts. The diazadithiafulvalenium radical cations trap primary carbon radicals successfully. However, the diazadithiafulvalenium salts which form, undergo rapid ring fragmentation in contrast to their tetrathia counterparts.

引用

页码：3637 / 3643

页数：7

共 16 条

[1] SIR92 - a program for automatic solution of crystal structures by direct methods [J].

ALTOMARE, A ;

CASCARANO, G ;

GIACOVAZZO, G ;

GUAGLIARDI, A ;

BURLA, MC ;

POLIDORI, G ;

CAMALLI, M .

JOURNAL OF APPLIED CRYSTALLOGRAPHY, 1994, 27 :435-435

[2] COMPETING [1,3]-SIGMATROPIC AND [3,3]-SIGMATROPIC REARRANGEMENTS OF ELECTRON-RICH OLEFINS [J].

BALDWIN, JE ;

WALKER, JA .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1974, 96 (02) :596-597

[3] A novel total synthesis of (±)-aspidospermidine [J].

Callaghan, O ;

Lampard, C ;

Kennedy, AR ;

Murphy, JA .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1999, (08) :995-1001

[4] COPPER(I) CATALYSIS OF OLEFIN PHOTOREACTIONS .15. SYNTHESIS OF CYCLOBUTANATED BUTYROLACTONES VIA COPPER(I)-CATALYZED INTERMOLECULAR PHOTOCYCLOADDITIONS OF HOMOALLYL VINYL OR DIALLYL ETHERS [J].

GHOSH, S ;

RAYCHAUDHURI, SR ;

SALOMON, RG .

JOURNAL OF ORGANIC CHEMISTRY, 1987, 52 (01) :83-90

[5] THE REACTION OF 3-METHYLTHIAZOLIUM DERIVATIVES WITH SUPEROXIDE [J].

ITOH, T ;

NAGATA, K ;

OKADA, M ;

OHSAWA, A .

TETRAHEDRON, 1993, 49 (22) :4859-4870

[6] Reactions of arenediazonium salts with diazadithiafulvalenes [J].

Koizumi, T ;

Bashir, N ;

Murphy, JA .

TETRAHEDRON LETTERS, 1997, 38 (43) :7635-7638

[7] TETRATHIAFULVALENE AS A CATALYST FOR RADICAL POLAR CROSSOVER REACTIONS [J].

LAMPARD, C ;

MURPHY, JA ;

LEWIS, N .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1993, (03) :295-297

[8]

*MOL STRUCT CORP, 1992, TEXS VERS 1 6 CRYST

[9]

MURPHY JA, 1995, J CHEM SOC P1, P623, DOI DOI 10.1039/P19950000623

[10]

PATRO BS, UNPUB

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