Arc-melting synthesis of BN nanocapsules from B/Al, TiB2 and VB2

被引：17

作者：

Narita, I ^{[1
]}

Oku, T ^{[1
]}

机构：

[1] Osaka Univ, Inst Sci & Ind Res, Osaka 5670047, Japan

来源：

DIAMOND AND RELATED MATERIALS | 2002年 / 11卷 / 3-6期

关键词：

nitride; nanocapsules; HREM; SQUID;

D O I：

10.1016/S0925-9635(01)00540-4

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Nanoparticles of AlB10, TiN and VN encapsulated by boron nitride (BN) layers were synthesized by an arc-melting method in a N-2/Ar gas mixture from boron/Al powder compacts, TiB2 and VB2, respectively. From high-resolution electron microscopy observations, formation mechanisms of BN nanocapsules were proposed, and BN tube-like structures were also produced. Magnetization of BN nanocapsules with TiN nanoparticles showed a spin-glass-like behavior. The present work indicates that Al, Ti and V could be a good catalyst to produce BN nanocapsules, nanocages and nanotubes by the arc melting method. (C) 2002 Elsevier Science B.V All rights reserved.

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收藏

页码：949 / 952

页数：4

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