Crystal structure, molecular dynamics, and polar properties of pyridinium fluorochromate

被引:31
作者
Pajak, Z [1 ]
Maluszynska, H [1 ]
Szafranska, B [1 ]
Czarnecki, P [1 ]
机构
[1] Adam Mickiewicz Univ Poznan, Inst Phys, Poznan, Poland
关键词
D O I
10.1063/1.1501477
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The crystal and molecular structure of pyridinium fluorochromate has been determined at 293, 240, and 150 K by x-ray diffraction. All three phases are orthorhombic with the following sequence of space groups and solid-solid phase transitions disclosed also by differential thermal analysis and differential scanning calorimetry, Cmcm-->258 K Cmc2(1)-->224 K Pbca. Only the low temperature phase is well ordered while the two high temperature phases reveal molecular disorder of both pyridinium and fluorochromate ions. H-1 and F-19 nuclear magnetic resonance study has been performed as a function of temperature to describe molecular dynamics of both ions. The dielectric and pyroelectric measurements together with these results allow us to characterize the low temperature phase III as antiferroelectric, the mesophase II as ferroelectric, with the Curie point at 258 K, and the high temperature phase I as paraelectric. (C) 2002 American Institute of Physics.
引用
收藏
页码:5303 / 5310
页数:8
相关论文
共 17 条
[1]  
[Anonymous], 1985, PRINCIPLES NUCL MAGN
[2]   Ferroelectricity and phase transitions in pyridinium periodate single crystal [J].
Czapla, Z ;
Dacko, S ;
Kosturek, B .
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION A-A JOURNAL OF PHYSICAL SCIENCES, 2000, 55 (11-12) :891-894
[3]   FERROELECTRIC PROPERTIES OF PYRIDINIUM TETRAFLUOROBORATE [J].
CZARNECKI, P ;
NAWROCIK, W ;
PAJAK, Z ;
WASICKI, J .
PHYSICAL REVIEW B, 1994, 49 (02) :1511-1512
[4]   FERROELECTRIC PROPERTIES OF PYRIDINIUM PERCHLORATE [J].
CZARNECKI, P ;
NAWROCIK, W ;
PAJAK, Z ;
WASICKI, J .
JOURNAL OF PHYSICS-CONDENSED MATTER, 1994, 6 (26) :4955-4960
[5]   ON ENANTIOMORPH-POLARITY ESTIMATION [J].
FLACK, HD .
ACTA CRYSTALLOGRAPHICA SECTION A, 1983, 39 (NOV) :876-881
[6]   Discovery of dipolar-glassy state in a newly found solid-solution system of C5NH6(BF4)1-x(PF6)x [J].
Hanaya, M ;
Nomoto, M ;
Miura, T ;
Oguni, M .
SOLID STATE COMMUNICATIONS, 2000, 115 (02) :57-62
[7]   CRYSTAL-STRUCTURE OF PYRIDINIUM IODIDE [J].
HARTL, H .
ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1975, 31 (JUN15) :1781-1783
[8]   H-1-NMR AND CL-35 NQR STUDIES ON THE MOTION OF PYRIDINIUM IONS IN CRYSTALLINE PYRIDINIUM TETRACHLORO AURATE(III) AND TETRABROMOAURATE(III) - (PYH)AUCL4, (PYH)AUBR4 [J].
ITO, Y ;
ASAJI, T ;
IKEDA, R ;
NAKAMURA, D .
BERICHTE DER BUNSEN-GESELLSCHAFT-PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 1988, 92 (08) :885-891
[9]  
Pajak Z, 2000, J CHEM PHYS, V113, P848, DOI 10.1063/1.481860
[10]  
Pajak Z, 1998, J CHEM PHYS, V109, P6420, DOI 10.1063/1.477286