Surface characterizations of conductive poly(methyl methacrylate)/polypyrrole composites

被引:26
作者
Omastová, M
Simon, F
机构
[1] Slovak Acad Sci, Inst Polymer, Bratislava 84236, Slovakia
[2] Inst Polymer Res Dresden, D-01069 Dresden, Germany
关键词
D O I
10.1023/A:1004728502591
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The composites of poly(methyl methacrylate) and polypyrrole (PMMA/PPy) were prepared by a chemical oxidation of pyrrole in a PMMA latex medium resulting in a network like structure of polypyrrole embedded in the insulating polymer matrix. Water was used as the dispersion medium. The content of polypyrrole was determined by elemental analysis as varying from 0.25 wt.% to 10 wt.%. The electrical conductivity of prepared composites depends on the concentration of polypyrrole and reached values of between 1 x 10(-9) S/cm to 0.1 S/cm The surface of powder form of PMMA/PPy composites was characterized by X-ray photoelectron spectroscopy (XPS) and by scanning electron microscopy (SEM). The antistatic properties of compression moulding form of composites were tested. (C) 2000 Kluwer Academic Publishers.
引用
收藏
页码:1743 / 1749
页数:7
相关论文
共 36 条
[1]   A solvent effect on the morphology of PMMA-coated polypyrrole surfaces [J].
Abel, ML ;
Camalet, JL ;
Chehimi, MM ;
Watts, JF ;
Zhdan, PA .
SYNTHETIC METALS, 1996, 81 (01) :23-31
[2]   EFFECT OF ACID-BASE INTERACTIONS ON THE ADSORPTION OF PMMA ON CHLORIDE-DOPED POLYPYRROLE FROM NEUTRAL, ACIDIC AND BASIC SOLVENTS - AN XPS STUDY [J].
ABEL, ML ;
CHEHIMI, MM .
SYNTHETIC METALS, 1994, 66 (03) :225-233
[3]   CONDUCTING POLYMER COLLOIDAL SILICA COMPOSITES [J].
ARMES, SP ;
GOTTESFELD, S ;
BEERY, JG ;
GARZON, F ;
AGNEW, SF .
POLYMER, 1991, 32 (13) :2325-2330
[4]   Surface characterization of polyaniline-coated polystyrene latexes [J].
Barthet, C ;
Armes, SP ;
Chehimi, MM ;
Bilem, C ;
Omastova, M .
LANGMUIR, 1998, 14 (18) :5032-5038
[5]   HIGH-RESOLUTION MONOCHROMATED XPS OF POLY(METHYL METHACRYLATE) THIN-FILMS ON A CONDUCTING SUBSTRATE [J].
BEAMSON, G ;
BUNN, A ;
BRIGGS, D .
SURFACE AND INTERFACE ANALYSIS, 1991, 17 (02) :105-115
[6]  
Beamson G., 1992, ADV MATER, DOI DOI 10.1002/ADMA.19930051035
[7]  
BRIGGS D, 1990, PRACTICAL SURFACE AN, V1
[8]  
CHAN HSO, 1990, J MACROMOL SCI CHEM, VA27, P1081
[9]   ELECTRICALLY CONDUCTING ORGANIC FILMS AND BEADS BASED ON CONDUCTING LATEX-PARTICLES [J].
COOPER, EC ;
VINCENT, B .
JOURNAL OF PHYSICS D-APPLIED PHYSICS, 1989, 22 (11) :1580-1585
[10]   X-RAY PHOTOELECTRON SPECTROSCOPIC STUDIES OF POLYPYRROLE SYNTHESIZED WITH OXIDATIVE FE(III) SALTS [J].
KANG, ET ;
NEOH, KG ;
ONG, YK ;
TAN, KL ;
TAN, BTG .
MACROMOLECULES, 1991, 24 (10) :2822-2828