Palladium-catalyzed enantioselective carbonylative cyclization of aryl and alkenyl triflates with carbon monoxide

被引：44

作者：

Hayashi, T ^{[1
]}

Tang, J ^{[1
]}

Kato, K ^{[1
]}

机构：

[1] Kyoto Univ, Grad Sch Sci, Dept Chem, Sakyo Ku, Kyoto 6068502, Japan

来源：

ORGANIC LETTERS | 1999年 / 1卷 / 09期

关键词：

D O I：

10.1021/ol9902879

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

[GRAPHICS] A catalyst system based on Pd(OCOCF3)(2)/(S)-binap has been established to effect asymmetric carbonylative cyclization of prochiral o-allylaryl triflates and 2-allylalkenyl triflates with carbon monoxide to produce high yields of enantiomerically enriched cyclopentenones (up to 96% ee).

引用

页码：1487 / 1489

页数：3

共 18 条

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