Stabilization of benzene versus oligoacetylenes: not another scale for aromaticity

被引:8
作者
Baldridge, KK [1 ]
Siegel, JS [1 ]
机构
[1] Univ Zurich, Inst Organ Chem, CH-8006 Zurich, Switzerland
关键词
benzene; oligoacetylenes; aromaticity scale;
D O I
10.1002/poc.819
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The energies of a number of oligoacetylenes are compared in a homodesmic reaction with benzene. Assessment of the open vs closed form of a conjugated triene is presented along with a perspective on the pursuit of quantitative scales for 'aromaticity'. Copyright (C) 2004 John Wiley Sons, Ltd.
引用
收藏
页码:740 / 742
页数:3
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