Evidence for a NiI active species in the catalytic cross-coupling of alkyl electrophiles

被引：238

作者：

Anderson, TJ ^{[1
]}

Jones, GD ^{[1
]}

Vicic, DA ^{[1
]}

机构：

[1] Univ Arkansas, Dept Chem & Biochem, Fayetteville, AR 72701 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2004年 / 126卷 / 26期

关键词：

D O I：

10.1021/ja0483903

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Addition of terpyridine to (TMEDA)Ni(CH3)2 results in the high-yield formation of (terpyridyl)NiMe (3). This NiI organometallic complex was found to be capable of transferring its methyl group to iodocyclohexane to produce methylcyclohexane in high yield. Compound 3 can also serve as an initiator for the catalytic cross-coupling of alkyl electrophiles performed under Negishi-like conditions. Copyright © 2004 American Chemical Society.

引用

页码：8100 / 8101

页数：2

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