Luminescence properties of transparent hybrid thin film covalently linked with lanthanide complexes

被引：66

作者：

Li, HR ^{[1
]}

Fu, LS ^{[1
]}

Lin, J ^{[1
]}

Zhang, HJ ^{[1
]}

机构：

[1] Chinese Acad Sci, Changchun Inst Appl Chem, Key Lab Rare Earth Chem & Phys, Changchun 130022, Peoples R China

来源：

THIN SOLID FILMS | 2002年 / 416卷 / 1-2期

基金：

中国国家自然科学基金;

关键词：

luminescence properties; hybrid; thin film; lanthanide complexes;

D O I：

10.1016/S0040-6090(02)00291-2

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Novel hybrid thin films covalently doped with Eu3+ (Tb3+) have been prepared via direct routes involving co-condensation of tetraethoxysilane and phen-Si in the presence of Eu3+ (Tb3+) by spin-casting and their luminescence properties have been investigated in detail. Lanthanide ions can be sensitized by anchored phenanthroline in hybrid thin films. Excitation at the ligand absorption wavelength (272 nm) resulted in the strong emission of the lanthanide ions i.e. Eu3+ D-5(0)-F-7(J) (J=0, 1, 2, 3, 4) emission lines and Tb3+ D-5(4)-F-7(J) (J = 6, 5, 4, 3) due to the energy transfer from the ligands to the lanthanide ions. (C) 2002 Elsevier Science B.V. All rights reserved.

引用

页码：197 / 200

页数：4

共 22 条

[1]

Bekiari V, 1998, ADV MATER, V10, P1455, DOI 10.1002/(SICI)1521-4095(199812)10:17<1455::AID-ADMA1455>3.0.CO

[2]

2-D

[3]

FORSTER T, 1949, Z NATURFORSCH A, V4, P321

[4] Preparation and luminescence properties of the ternary europium complex incorporated into an inorganic polymer matrix by a sol-gel method [J].