The Heck reaction in ionic liquids: A multiphasic catalyst system

被引:515
作者
Carmichael, AJ [1 ]
Earle, MJ [1 ]
Holbrey, JD [1 ]
McCormac, PB [1 ]
Seddon, KR [1 ]
机构
[1] Queens Univ Belfast, Sch Chem, Belfast BT9 5AG, Antrim, North Ireland
关键词
D O I
10.1021/ol9907771
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
[GRAPHICS] Heck coupling of aryl halides or benzoic anhydride with alkenes can be performed with excellent yields in room-temperature ionic liquids, which provide a medium that dissolves the palladium catalyst and allows the product and byproducts to be easily separated. Consequently, the catalyst and ionic liquid can be recycled and reused.
引用
收藏
页码:997 / 1000
页数:4
相关论文
共 33 条
[1]   Stereoselective hydrogenation reactions in chloroaluminate(III) ionic liquids: a new method for the reduction of aromatic compounds [J].
Adams, CJ ;
Earle, MJ ;
Seddon, KR .
CHEMICAL COMMUNICATIONS, 1999, (11) :1043-1044
[2]  
Adams CJ, 1998, CHEM COMMUN, P2097
[3]  
ADAMS CJ, 1998, Patent No. 07679
[4]   Identification of the effective palladium(0) catalytic species generated in situ from mixtures of Pd(dba)(2) and bidentate phosphine ligands. Determination of their rates and mechanism in oxidative addition [J].
Amatore, C ;
Broeker, G ;
Jutand, A ;
Khalil, F .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1997, 119 (22) :5176-5185
[5]   Role of dba in the reactivity of palladium(0) complexes generated in situ from mixtures of Pd(dba)2 and phosphines [J].
Amatore, C ;
Jutand, A .
COORDINATION CHEMISTRY REVIEWS, 1998, 178 :511-528
[6]  
[Anonymous], FRIEDELCRAFTS CHEM
[7]  
BADER A, 1991, Patent No. 0459258
[8]   PALLADACYCLES AS EFFICIENT CATALYSTS FOR ARYL COUPLING REACTIONS [J].
BELLER, M ;
FISCHER, H ;
HERRMANN, WA ;
OFELE, K ;
BROSSMER, C .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1995, 34 (17) :1848-1849
[9]   PALLADIUM-CATALYZED ARYLATION AND VINYLATION OF 1,4-DIENES [J].
BENDER, DD ;
STAKEM, FG ;
HECK, RF .
JOURNAL OF ORGANIC CHEMISTRY, 1982, 47 (07) :1278-1284
[10]   Green processing using ionic liquids and CO2 [J].
Blanchard, LA ;
Hancu, D ;
Beckman, EJ ;
Brennecke, JF .
NATURE, 1999, 399 (6731) :28-29