Mapping molecular dynamics (Na2) in intense laser fields:: another dimension to femtochemistry

被引:48
作者
Frohnmeyer, T
Hofmann, M
Strehle, M
Baumert, T
机构
[1] Univ Kassel, Fachbereich Phys, D-34132 Kassel, Germany
[2] Univ Wurzburg, Inst Phys, D-97074 Wurzburg, Germany
关键词
D O I
10.1016/S0009-2614(99)00895-7
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Time-resolved photoelectron spectroscopy in combination with femtosecond pump-probe and molecular beam techniques is used to map the vibrational wavepacket motion along the internuclear coordinate. Using an attenuated femtosecond pump pulse and a probe pulse with variable intensity, the influence of high laser fields on the molecular potential is detected sensitive to the internuclear distance. We observe electronic transitions at non-Franck-Condon allowed areas which are attributed to light-induced potentials. (C) 1999 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:447 / 454
页数:8
相关论文
共 29 条
[1]  
[Anonymous], FEMTOCHEMISTRY
[2]   Femtosecond pump-probe photoelectron spectroscopy: Mapping of vibrational wave-packet motion [J].
Assion, A ;
Geisler, M ;
Helbing, J ;
Seyfried, V ;
Baumert, T .
PHYSICAL REVIEW A, 1996, 54 (06) :R4605-R4608
[3]  
ASSION A, 1996, SPRINGER SERIES CHEM, V270
[4]   Molecules in intense femtosecond laser fields [J].
Baumert, T ;
Gerber, G .
PHYSICA SCRIPTA, 1997, T72 :53-68
[5]   FEMTOSECOND TIME-RESOLVED WAVE PACKET MOTION IN MOLECULAR MULTIPHOTON IONIZATION AND FRAGMENTATION [J].
BAUMERT, T ;
BUHLER, B ;
GROSSER, M ;
THALWEISER, R ;
WEISS, V ;
WIEDENMANN, E ;
GERBER, G .
JOURNAL OF PHYSICAL CHEMISTRY, 1991, 95 (21) :8103-8110
[6]   Coherent control with femtosecond laser pulses [J].
Baumert, T ;
Helbing, J ;
Gerber, G ;
Woste, L ;
Zewail, AH ;
Troe, J ;
Manz, J ;
Kobayashi, T ;
Letokhov, VS ;
Even, U ;
Chergui, M ;
Neumark, DM ;
Rice, SA .
CHEMICAL REACTIONS AND THEIR CONTROL ON THE FEMTOSECOND TIME SCALE XXTH SOLVAY CONFERENCE ON CHEMISTRY, 1997, 101 :47-82
[7]   HIGH LASER FIELD EFFECTS IN MULTIPHOTON IONIZATION OF NA2 - EXPERIMENT AND QUANTUM CALCULATIONS [J].
BAUMERT, T ;
ENGEL, V ;
MEIER, C ;
GERBER, G .
CHEMICAL PHYSICS LETTERS, 1992, 200 (05) :488-494
[8]   FEMTOSECOND TIME-RESOLVED MOLECULAR MULTIPHOTON IONIZATION - THE NA2 SYSTEM [J].
BAUMERT, T ;
GROSSER, M ;
THALWEISER, R ;
GERBER, G .
PHYSICAL REVIEW LETTERS, 1991, 67 (27) :3753-3756
[9]  
BAUMERT T, 1994, ISRAEL J CHEM, V34, P103
[10]   Nonadiabatic dynamics in polyatomic systems studied by femtosecond time-resolved photoelectron spectroscopy [J].
Blanchet, V ;
Stolow, A .
JOURNAL OF CHEMICAL PHYSICS, 1998, 108 (11) :4371-4374