Inclusion-water-cluster in a three-dimensional superlattice of gold nanoparticles

被引:48
作者
Wang, SH [1 ]
Yao, H [1 ]
Sato, S [1 ]
Kimura, K [1 ]
机构
[1] Himeji Inst Technol, Dept Mat Sci, Kamigori, Hyogo 6781297, Japan
关键词
D O I
10.1021/ja031822+
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Three-dimensional particle crystals made of dicarboxylic thiolate (MSA)-stabilized gold nanoparticles were formed at an air/water interface. FTIR spectra of this supracrystal showed that three well-resolved peaks existed from 3400 to 3550 cm-1 just falling in a region of OH stretching vibrational mode. Precise analysis showed that all these peaks originated from the water cluster included in the interstice of a particle crystal. Copyright © 2004 American Chemical Society.
引用
收藏
页码:7438 / 7439
页数:2
相关论文
共 24 条
[1]   WHY IS WATER BLUE [J].
BRAUN, CL ;
SMIRNOV, SN .
JOURNAL OF CHEMICAL EDUCATION, 1993, 70 (08) :612-615
[2]   Structure and spectra of three-dimensional (H2O)n clusters, n = 8, 9, 10 [J].
Buck, U ;
Ettischer, I ;
Melzer, M ;
Buch, V ;
Sadlej, J .
PHYSICAL REVIEW LETTERS, 1998, 80 (12) :2578-2581
[3]   Synthesis and characterization of carboxylate-modified gold nanoparticle powders dispersible in water [J].
Chen, SH ;
Kimura, K .
LANGMUIR, 1999, 15 (04) :1075-1082
[4]   Nanocrystal superlattices [J].
Collier, CP ;
Vossmeyer, T ;
Heath, JR .
ANNUAL REVIEW OF PHYSICAL CHEMISTRY, 1998, 49 :371-404
[5]  
COLTHUP NB, 1990, INTRO INFRARED RAMAN, P256
[6]   Supracrystals made of nanocrystals. 2. Growth on HOPG substrate [J].
Courty, A ;
Araspin, O ;
Fermon, C ;
Pileni, MP .
LANGMUIR, 2001, 17 (05) :1372-1380
[7]   LANGMUIR-BLODGETT MANIPULATION OF SIZE-SELECTED CDSE NANOCRYSTALLITES [J].
DABBOUSI, BO ;
MURRAY, CB ;
RUBNER, MF ;
BAWENDI, MG .
CHEMISTRY OF MATERIALS, 1994, 6 (02) :216-219
[8]   PREPARATION OF ORDERED COLLOID MONOLAYERS BY ELECTROPHORETIC DEPOSITION [J].
GIERSIG, M ;
MULVANEY, P .
LANGMUIR, 1993, 9 (12) :3408-3413
[9]   Three-dimensional hexagonal close-packed superlattice of passivated Ag nanocrystals [J].
Harfenist, SA ;
Wang, ZL ;
Whetten, RL ;
Vezmar, I ;
Alvarez, MM .
ADVANCED MATERIALS, 1997, 9 (10) :817-&
[10]   THEORETICAL-STUDY OF WATER CLUSTERS - OCTAMER [J].
JENSEN, JO ;
KRISHNAN, PN ;
BURKE, LA .
CHEMICAL PHYSICS LETTERS, 1995, 246 (1-2) :13-19