New effective synthons for supramolecular self-assembly of meso-carboxyphenylporphyrins

被引:65
作者
Diskin-Posner, Y [1 ]
Dahal, S [1 ]
Goldberg, I [1 ]
机构
[1] Tel Aviv Univ, Sackler Fac Exact Sci, Sch Chem, IL-69978 Tel Aviv, Israel
关键词
D O I
10.1039/b001189o
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Tesselation of new supramolecular motifs of the tetra(4-carboxyphenyl)porphyrin building blocks by metal ion templates has been demonstrated in crystals, characterizing the square-planar [Na+.(-COOH)(4). X-] and the tetrahedral [Zn2+.(-COOH)(2).(-COO-)(2)] molecular recognition elements for effective multiporphyrin assembly.
引用
收藏
页码:585 / 586
页数:2
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