A polyfunctional lewis acid with antifacial μ3-N,N-dimethylformamide ligands in [(o-HgC6F4)3(dmf)2]

被引：29

作者：

Baldamus, J

Deacon, GB

Hey-Hawkins, E

Junk, PC

Martin, C

机构：

[1] Monash Univ, Sch Chem, Clayton, Vic 3800, Australia

[2] Univ Leipzig, Inst Anorgan Chem, D-04103 Leipzig, Germany

来源：

AUSTRALIAN JOURNAL OF CHEMISTRY | 2002年 / 55卷 / 03期

关键词：

D O I：

10.1071/CH02039

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In [(o-HgC6F4)(3) (dmf)(2)], the cyclotrimeric tetrafluoro-o-phenylenemercury(II) molecule is ligated by two mu(3)-dmf-O molecules above (Hg-O 2.837(7), 2.895(5), 3.036(5) Angstrom) and below (Hg-O 2.820(5), 2.863(6), 2.927(6) Angstrom) the Hg-3 plane with the two oxygens and the three mercury atoms in a trigonal bipyramidal arrangement about the centroid of the Hg-3 plane.

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页码：195 / 198

页数：4

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