Decarboxylation of 2,2′-bipyridinyl-4,4′-dicarboxylic acid diethyl ester during microwave synthesis of the corresponding trichelated ruthenium complex

被引：14

作者：

Anderson, Thomas J.

Scott, Jill R.

Millett, Frank

Durham, Bill ^{[1
]}

机构：

[1] Univ Arkansas, Dept Chem & Biochem, Fayetteville, AR 72701 USA

[2] Idaho Natl Lab, Idaho Falls, ID 83415 USA

来源：

INORGANIC CHEMISTRY | 2006年 / 45卷 / 10期

关键词：

D O I：

10.1021/ic060008v

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Microwave reaction of RuCl3 with 2,2-bipyridinyl-4,4-dicarboxylic acid diethyl ester (debpy) in ethylene glycol generated Ru(bpy)(3)(2+) instead of the expected Ru(debpy)(3)(2+). Gas chromatography-mass spectrometry analysis of the headspace revealed CO2, and Ru(bpy)(3)(2+) was recovered from the filtrate. Further experiments suggest that RuCl3 decarboxylates debpy during microwave synthesis.

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页码：3843 / 3845

页数：3

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