Metal-catalyzed bond reorganization of 1,3-diynes

被引：33

作者：

Cho, Eun Jin ^{[1
]}

Kim, Mansuk ^{[1
]}

Lee, Daesung ^{[1
]}

机构：

[1] Univ Wisconsin, Dept Chem, Madison, WI 53706 USA

来源：

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY | 2006年 / 2006卷 / 14期

关键词：

rearrangement; 1,3-diyne; 1,5-dien-3-yne; metal carbene; metallotropic [1,3]-shift;

D O I：

10.1002/ejoc.200600332

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

1,3-Diynes possessing propargylic heteroatom substituents provide functionalized 1,5-dien-3-ynes when catalyzed by platinum and gold. This rearrangement implies the involvement of metallotropic [1,3]-shift of the intermediate alkynyl metal carbene species. (c) Wiley-VCH Verlag GmbH & Co.

引用

页码：3074 / 3078

页数：5

共 64 条

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