Orientation of native cellulose in an electric field

被引:168
作者
Bordel, Damien [1 ]
Putaux, Jean-Luc [1 ]
Heux, Laurent [1 ]
机构
[1] Univ Grenoble 1, CERMAV, CNRS, ICMG, F-38041 Grenoble 9, France
关键词
D O I
10.1021/la0600402
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Native cellulose has been oriented in an ac electric field at both the macroscopic and colloidal level. Ramie fiber fragments suspended in chloroform have been shown to point along the field. Cellulose microcrystal suspensions in cyclohexane have also been allowed to evaporate in an electric field and have exhibited a high degree of orientation when further examined by TEM and electron diffraction. Similarly, cellulose whisker suspensions showed increasing birefringence with increasing field strength and displayed interference Newton colors that saturated at around 2000 V cm(-1). A high degree of order of this suspension was also obtained by evaluating the induced birefringence with color charts.
引用
收藏
页码:4899 / 4901
页数:3
相关论文
共 17 条
[1]   ELECTRIC BIREFRINGENCE IN CONCENTRATED-SOLUTIONS OF TOBACCO MOSAIC-VIRUS [J].
ASAI, H ;
WATANABE, N .
BIOPOLYMERS, 1976, 15 (02) :383-392
[2]   LIGHT-SCATTERING FROM SEMIDILUTE DISPERSIONS OF NONSPHERICAL LATEX-PARTICLES SUBJECTED TO AN ELECTRIC-FIELD [J].
BALOCH, MK ;
VANDEVEN, TGM .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 1990, 135 (02) :594-597
[3]  
Bloss F.D., 1961, INTRO METHODS OPTICA
[4]   Effects of ionic strength on the isotropic-chiral nematic phase transition of suspensions of cellulose crystallites [J].
Dong, XM ;
Kimura, T ;
Revol, JF ;
Gray, DG .
LANGMUIR, 1996, 12 (08) :2076-2082
[5]   Shear-induced orientation phenomena in suspensions of cellulose microcrystals, revealed by small angle X-ray scattering [J].
Ebeling, T ;
Paillet, M ;
Borsali, R ;
Diat, O ;
Dufresne, A ;
Cavaillé, JY ;
Chanzy, H .
LANGMUIR, 1999, 15 (19) :6123-6126
[6]   ELECTROOPTICAL STUDY OF THE EFFECT OF SURFACTANT ON ATTAPULGITE CLAY SOL STABILITY [J].
FAIREY, RC ;
JENNINGS, BR .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 1982, 85 (01) :205-215
[7]   ELECTRIC BIREFRINGENCE OF POLY(TETRAFLUOROETHYLENE) WHISKERS [J].
FOSTER, KR ;
OSBORN, AJ ;
WOLFE, MS .
JOURNAL OF PHYSICAL CHEMISTRY, 1992, 96 (13) :5483-5487
[8]  
HERMAN PH, 1949, PHYS CHEM CELLULOSE
[9]   Nonflocculating and chiral-nematic self-ordering of cellulose microcrystals suspensions in nonpolar solvents [J].
Heux, L ;
Chauve, G ;
Bonini, C .
LANGMUIR, 2000, 16 (21) :8210-8212
[10]   Magnetic alignment of the chiral nematic phase of a cellulose microfibril suspension [J].
Kimura, F ;
Kimura, T ;
Tamura, M ;
Hirai, A ;
Ikuno, M ;
Horii, F .
LANGMUIR, 2005, 21 (05) :2034-2037