A scalable CVD method for the synthesis of single-walled carbon nanotubes with high catalyst productivity

被引:351
作者
Su, M [1 ]
Zheng, B [1 ]
Liu, J [1 ]
机构
[1] Duke Univ, Dept Chem, Durham, NC 27708 USA
关键词
D O I
10.1016/S0009-2614(00)00422-X
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Single-walled carbon nanotubes (SWNT) are known to possess superior mechanical and electronic properties. However, the lack of methods for large-scale preparation limits fundamental research and application development of this unique material. Among all methods currently used for SWNT preparation, chemical vapor deposition (CVD) method represents the best hope for large-scale production. However, current CVD method has limited catalyst productivity (similar to 40% the weight of the starting catalyst). Here we report an improved CVD method for preparation of SWNTs with high productivity using a never aerogel supported Fe/Mo catalyst. The total amount of high-quality SWNTs produced is greater than 200% the weight of the catalysts. (C) 2000 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:321 / 326
页数:6
相关论文
共 36 条
  • [1] ON THE MECHANISM OF THE FISCHER-TROPSCH SYNTHESIS INVOLVING UNREDUCED IRON CATALYST
    BLANCHARD, F
    REYMOND, JP
    POMMIER, B
    TEICHNER, SJ
    [J]. JOURNAL OF MOLECULAR CATALYSIS, 1982, 17 (2-3): : 171 - 181
  • [2] Cassell AM, 1999, J PHYS CHEM B, V103, P6484, DOI 10.1021/jp990957sCCC:$18.00
  • [3] Large-scale and low-cost synthesis of single-walled carbon nanotubes by the catalytic pyrolysis of hydrocarbons
    Cheng, HM
    Li, F
    Su, G
    Pan, HY
    He, LL
    Sun, X
    Dresselhaus, MS
    [J]. APPLIED PHYSICS LETTERS, 1998, 72 (25) : 3282 - 3284
  • [4] Single-wall nanotubes produced by metal-catalyzed disproportionation of carbon monoxide
    Dal, HJ
    Rinzler, AG
    Nikolaev, P
    Thess, A
    Colbert, DT
    Smalley, RE
    [J]. CHEMICAL PHYSICS LETTERS, 1996, 260 (3-4) : 471 - 475
  • [5] Dresselhaus M. S., 1988, GRAPHITE FIBERS FILA, DOI DOI 10.1007/978-3-642-83379-3
  • [6] Dresselhaus M. S., 1996, SCI FULLERENES CARBO
  • [7] Self-oriented regular arrays of carbon nanotubes and their field emission properties
    Fan, SS
    Chapline, MG
    Franklin, NR
    Tombler, TW
    Cassell, AM
    Dai, HJ
    [J]. SCIENCE, 1999, 283 (5401) : 512 - 514
  • [8] SCALE-UP STUDIES ON AN ALUMINA AEROGEL CATALYST SUPPORT
    FANELLI, AJ
    VERMA, S
    ENGELMANN, T
    BURLEW, JV
    [J]. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 1991, 30 (01) : 126 - 129
  • [9] Synthesis of single-walled carbon nanotubes using binary (Fe, Co, Ni) alloy nanoparticles prepared in situ by the reduction of oxide solid solutions
    Flahaut, E
    Govindaraj, A
    Peigney, A
    Laurent, C
    Rousset, A
    Rao, CNR
    [J]. CHEMICAL PHYSICS LETTERS, 1999, 300 (1-2) : 236 - 242
  • [10] FRICKE J, 1986, AEROGELS