Cobalt(III) α-dimethylglyoximates [Co(DH)2(PY)2]2SiF6 •10H2O and [Co(DH)2(Thio)2]2SiF6 • 2H2O • C2H5OH:: Synthesis and structure

被引：9

作者：

Bourosh, PN

Coropceanu, EB

Simonov, YA

Gdaniec, M

Bologa, OA

Gerbeleu, NV

机构：

[1] Moldavian Acad Sci, Inst Appl Phys, MD-2028 Kishinev, Moldova

[2] Moldavian Acad Sci, Inst Chem, MD-2028 Kishinev, Moldova

[3] Adam Mickiewicz Univ Poznan, PL-60780 Poznan, Poland

来源：

RUSSIAN JOURNAL OF COORDINATION CHEMISTRY | 2002年 / 28卷 / 09期

关键词：

Hydrogen; Physical Chemistry; 2H2O; Cobalt; Diffraction Analysis;

D O I：

10.1023/A:1020095101054

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

[Co(DH)(2)(PY)(2)}(2)SiF6 . 10H(2)O and [Co(DH)(2)(Thio)(2)](2)SiF6 . 2H(2)O . C2H5OH complexes are synthesized and characterized by X-ray diffraction analysis. Two radicals of alpha-glyoxime linked by hydrogen O-H...O bonds lie in the equatorial plane of the octahedral Co(III) complexes. Intramolecular (pi-pi and N-H...O) and intermolecular (O-H...F, O-H...O, N-H...F, N-H...O, N-H...S) interactions are discovered in the crystal. The influence of nonvalence interactions on the structures is discussed.

引用

页码：647 / 655

页数：9

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