Theoretical chemistry of gold

被引：1582

作者：

Pyykkö, P ^{[1
]}

机构：

[1] Univ Erlangen Nurnberg, Lehrstuhl Theoret Chem, D-91058 Erlangen, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2004年 / 43卷 / 34期

关键词：

aurophilicity; closed-shell interactions; gold; relativistic effects; theoretical chemistry;

D O I：

10.1002/anie.200300624

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Gold is an element whose unique properties are strongly influenced by relativistic effects. A large body of appropriate calculations now exist and their main conclusions are summarized. The theoretical interpretation of the aurophilic attraction is discussed in detail.

引用

页码：4412 / 4456

页数：45

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