Identification of steel by X-ray fluorescence analysis with a pyroelectric X-ray generator

被引:24
作者
Ida, H [1 ]
Kawai, J
机构
[1] Kyoto Univ, Dept Mat Sci & Engn, Sakyo Ku, Kyoto 6068501, Japan
[2] Kyoto Pref Police HQ, Forens Sci Lab, Kamigyo Ku, Kyoto 6028550, Japan
关键词
x-ray fluorescence analysis; pyroelectric crystal; x-ray generator; steel;
D O I
10.1007/s00216-004-2649-3
中图分类号
Q5 [生物化学];
学科分类号
071010 ; 081704 ;
摘要
An application of X-ray fluorescence analysis with a pyroelectric X-ray generator is presented. Steel standard samples were identified by X-ray fluorescence analysis with this novel X-ray generator to check its capability for performing qualitative and quantitative analysis as an X-ray source for X-ray fluorescence spectrometers. Cr, Ni, V, Co, and W were detected in steel standard samples. V and Cr can be detected even when the content is below 1%. Although it is difficult to detect minor elements because of the low power of the excitation X-rays, it is possible to identify the analyzed samples on the basis of major elements at the percentage level. The pyroelectric X-ray generator is very suitable for portable X-ray fluorescence spectrometers.
引用
收藏
页码:735 / 738
页数:4
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