Novel anion exchange resin-based catalyst for liquid-phase methanol synthesis at 373-393 K

被引：3

作者：

Aika, K

Kobayashi, H

Harada, K

Inazu, K

机构：

[1] Tokyo Inst Technol, Dept Environm Chem, Midori Ku, Yokohama, Kanagawa 2268502, Japan

[2] Tokyo Inst Technol, Interdisciplinary Grad Sch Sci & Engn, Midori Ku, Yokohama, Kanagawa 2268502, Japan

来源：

CHEMISTRY LETTERS | 2004年 / 33卷 / 10期

关键词：

D O I：

10.1246/cl.2004.1252

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A thermo-stable anion exchange resin-Raney Cu system was found as the most effective solid catalyst for low-temperalure liquid-phase methanol synthesis at 373 to 393 K under 5.0 MPa of syngas (2H(2)/CO). With the catalyst (20 mL of the resin and 2.0 g of Cu) suspended in methanol solution 72% of CO was converted to methanol (70%) and methyl formate (HCOOCH3) (30%) in 4 h.

引用

页码：1252 / 1253

页数：2

共 10 条

[1]

Carlini C, 1998, STUD SURF SCI CATAL, V119, P491

[2] Methanol carbonylation to methyl formate catalyzed by strongly basic resins [J].