Dendrimer-supported oligothiophene synthesis:: Aliphatic ether dendrimers in the preparation of oligothiophenes with minimal substitution

被引：29

作者：

Malenfant, PRL ^{[1
]}

Jayaraman, M ^{[1
]}

Fréchet, JMJ ^{[1
]}

机构：

[1] Univ Calif Berkeley, Dept Chem, Berkeley, CA 94720 USA

来源：

CHEMISTRY OF MATERIALS | 1999年 / 11卷 / 12期

关键词：

D O I：

10.1021/cm9905500

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The first dendrimer-supported synthesis of oligothiophenes is reported. The dendrimer serves both as a solubilizing group and a "handle" to facilitate the iterative synthesis of the oligothiophenes. The dendrimer-functionalized oligothiophenes with minimal ring substitution were found to have an extended conjugation compared to analogous oligomers having several linear alkyl chain solubilizing substituents.

引用

页码：3420 / +

页数：4

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