Synthesis, crystal structure and properties of manganese(II) hexafluoroacetylacetonates Mn(hfa)2(H2O)2 and KMn(hfa)3

被引：28

作者：

Troyanov, SI ^{[1
]}

Gorbenko, OY ^{[1
]}

Bosak, AA ^{[1
]}

机构：

[1] Moscow MV Lomonosov State Univ, Dept Chem, Moscow 119899, Russia

来源：

POLYHEDRON | 1999年 / 18卷 / 26期

关键词：

beta-diketonates; manganese(II); crystal structure; MOCVD;

D O I：

10.1016/S0277-5387(99)00288-0

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two manganese(II) hexafluoroacetylacetonate complexes, dihydrate, the Mn(hfa)(2)(H2O)(2) (1), and the bimetallic KMn(hfa)(3) (2) have been synthesized and characterized by X-ray single crystal structure analysis. They have a molecular structure and a polymeric structure, respectively. The high stability of 2 allowed sublimation without decomposition. It was then used as a precursor for MOCVD of fluoroperovskite, KMnF3. (C) 1999 Elsevier Science Ltd. All rights reserved.

引用

页码：3505 / 3509

页数：5

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