Constant-distance mode scanning potentiometry. 1. Visualization of calcium carbonate dissolution in aqueous solution

被引:42
作者
Etienne, M
Schulte, A
Mann, S
Jordan, G
Dietzel, LD
Schuhmann, W [1 ]
机构
[1] Ruhr Univ Bochum, Lehrstuhl Mol Neurobiochem, D-44780 Bochum, Germany
[2] Ruhr Univ Bochum, Inst Geol Mineral & Geophys, D-44780 Bochum, Germany
关键词
D O I
10.1021/ac0349227
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
Constant-distance mode scanning potentiometry was established by integrating potentiometric microsensors as ion-selective scanning probes into a SECM setup that was equipped with a piezoelectric shear force-based tip-to-sample distance control. The combination of specially designed micrometer-sized potentiometric tips with an advanced system for tip positioning allowed simultaneous acquisition of both topographic and potentiometric information at solid/liquid interfaces with high spatial resolution. The performance of the approach was evaluated by applying Ca2+-selective constant-distance mode potentiometry to monitor the dissolution of calcium carbonate occurring either at the (104) surface of calcite crystals or in proximity to the more complex surface of cross sections of a calcium carbonate shell of Mya arenaria exposed to slightly acidic aqueous solutions. Micrometer-scale heterogeneities in the apparent calcium activity profiles have successfully been resolved for both samples.
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页码:3682 / 3688
页数:7
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