Zeolitic Boron Imidazolate Frameworks

被引：213

作者：

Zhang, Jian ^{[2
]}

Wu, Too ^{[1
]}

Zhou, Cong ^{[1
]}

Chen, Shumei ^{[2
]}

Feng, Pingyun ^{[1
]}

Bu, Xianhui ^{[2
]}

机构：

[1] Univ Calif Riverside, Dept Chem, Riverside, CA 92521 USA

[2] Calif State Univ Long Beach, Dept Chem & Biochem, Long Beach, CA 90840 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2009年 / 48卷 / 14期

基金：

美国国家卫生研究院; 美国国家科学基金会;

关键词：

boron; imidazolates; metal-organic frameworks; microporous materials; zeolites; METAL-ORGANIC FRAMEWORKS; IONOTHERMAL SYNTHESIS; CRYSTAL-STRUCTURES; SOLIDS; CHEMISTRY; DESIGN; POLYMORPHISM; TOPOLOGIES; ISOMERISM; POLYMERS;

D O I：

10.1002/anie.200804169

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

B-hive? A family of crystalline materials analogous to porous AlPO 4 but based on boron imidazolate frameworks (BIFs) can be formed by the crosslinking of various presynthesized boron imidazolates with monovalent cations (Li+ and Cu+, see picture). This synthetic method is capable of generating a large variety of open frameworks, ranging from the four-connected zeolitic sodalite type to the three-connected chiral (10,3)-a type. © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：2542 / 2545

页数：4

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