Novel aggregation of fac(S)-[Rh(aet)(3)] by square-planar palladium(II): Crystal structure of spontaneously resolved (Rh3Pd2II)-Pd-III pentanuclear complex [Pd{Pd(aet)}{Rh(aet)(2)}{Rh(aet)(3)}(2)]Br-4 (aet equals 2-aminoethanethiolate)

被引：16

作者：

Konno, T

Sasaki, C

Okamoto, K

机构：

[1] Department of Chemistry, University of Tsukuba, Tsukuba

来源：

CHEMISTRY LETTERS | 1996年 / 11期

关键词：

D O I：

10.1246/cl.1996.977

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction of fac(S)-[Rh(aet)(3)] (aet = NH2CH2CH2S-) with pd(II) gave a novel S-bridged (Rh3Pd2II)-Pd-III pentanuclear complex, [Pd{Pd(aet)}{Rh(aet)(2)}{Rh(aet)(3)}(2)](4+) (1), of which bromide salt was spontaneously resolved. 1 was converted into [Pd{Pd(aet)}{Rh(aet)(NH2CH2CH2SCH3)}{Rh(aet)(3)}(2)](5+) (2) by methylation reaction.

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收藏

页码：977 / 978

页数：2

相关论文

共 20 条

[1] ELECTRONIC AND CIRCULAR DICHROISM SPECTRA OF POLYNUCLEAR 2-AMINOETHANETHIOL COMPLEXES [J].

BRUBAKER, GR ;

DOUGLAS, BE .

INORGANIC CHEMISTRY, 1967, 6 (08) :1562-&

[2]

BUSCH DH, 1962, INORG CHEM, V1, P884

[3] ELECTRON-SPIN RESONANCE STUDY OF IRON(III) AND RUTHENIUM(III) IN A TRINUCLEAR COMPLEX OF TRIS(2-MERCAPTOETHYLAMINE)COBALT(III) [J].

DESIMONE, RE ;

ONTKO, T ;

WARDMAN, L ;

BLINN, EL .

INORGANIC CHEMISTRY, 1975, 14 (06) :1313-1316

[4] SIGNIFICANCE TESTS ON CRYSTALLOGRAPHIC R FACTOR [J].

HAMILTON, WC .

ACTA CRYSTALLOGRAPHICA, 1965, 18 :502-&

[5] SYNTHESIS OF [CO(COL3)2]3+ BY HNO3 OXIDATION OF COL3 (L = -SCH2CH2NH2) AND INDUCED ELECTRON-TRANSFER - CRYSTAL-STRUCTURE OF [CO(COL3)2]2(SO4)CL4 [J].

HEEG, MJ ;

BLINN, EL ;

DEUTSCH, E .

INORGANIC CHEMISTRY, 1985, 24 (07) :1118-1120

[6]

JOHNSON DW, 1988, INORG CHIM ACTA, V151, P221

[7] A NEW CLASS OF S-BRIDGED POLYNUCLEAR COMPLEX - THE FORMATION AND CRYSTAL-STRUCTURE OF SPONTANEOUSLY RESOLVED [(RH(2-AMINOETHANETHIOLATE)3)4ZN3O]4+ [J].

KONNO, T ;

OKAMOTO, K ;

HIDAKA, J .

CHEMISTRY LETTERS, 1990, (07) :1043-1046

[8] PREPARATION, CHARACTERIZATION, AND SOME PROPERTIES OF A T-CAGE-TYPE S-BRIDGED RH4(III)ZN3(II) HEPTANUCLEAR COMPLEX WITH A DEFECTIVE [ZN3HO](5+) CORE - CRYSTAL-STRUCTURE OF SPONTANEOUSLY RESOLVED [(RH(AET)(3))4ZN3HO]BR-5 (AET=2-AMINOETHANETHIOLATE) [J].

KONNO, T ;

OKAMOTO, K ;

HIDAKA, J .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1994, 67 (01) :101-107

[9] PREPARATION AND SOME PROPERTIES OF [COIIORIII(RHIII(AET OR L-CYS-N,S)3)2]-TYPE S-BRIDGED TRINUCLEAR COMPLEXES [J].

KONNO, T ;

AIZAWA, S ;

OKAMOTO, K ;

HIDAKA, J .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1990, 63 (03) :792-798

[10] SYNTHESIS AND PROPERTIES OF LINEAR-TYPE S-BRIDGED RH(III)NI(II)RH(III) TRINUCLEAR COMPLEXES WITH 2-AMINOETHANETHIOLATE (AET) OR L-CYSTEINATE (L-CYS) - CRYSTAL-STRUCTURE OF [NI(RH(AET)(3))(2)](NO3)(2) [J].

KONNO, T ;

OKAMOTO, K .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1995, 68 (02) :610-615