Ring synthesis by stereoselective, methylene-free enyne cross metathesis

被引：38

作者：

Kulkarni, AA ^{[1
]}

Diver, ST ^{[1
]}

机构：

[1] SUNY Buffalo, Dept Chem, Buffalo, NY 14260 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2004年 / 126卷 / 26期

关键词：

D O I：

10.1021/ja0476922

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Tandem enyne metathesis between 1-alkynes and 1,5-cyclooctadiene or all-cis-1,4-polybutadiene resulted in a direct, one-step ring synthesis of cyclohexadienes by methylene-free metathesis. The use of methylene-free metathesis conditions provided apparent Z-selectivity in the intermolecular enyne metathesis step. Copyright © 2004 American Chemical Society.

引用

页码：8110 / 8111

页数：2

共 20 条

[1] [Anonymous], 2003, HDB METATHESIS
[2] Synthesis of cyclic polybutadiene via ring-opening metathesis polymerization: The importance of removing trace linear contaminants
Bielawski, CW
Benitez, D
Grubbs, RH
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (28) : 8424 - 8425
[3] Bielawski CW, 2000, ANGEW CHEM INT EDIT, V39, P2903, DOI 10.1002/1521-3773(20000818)39:16<2903::AID-ANIE2903>3.0.CO
[4] 2-Q
[5] Enyne metathesis (enyne bond reorganization)
Diver, ST
Giessert, AJ
[J]. CHEMICAL REVIEWS, 2004, 104 (03) : 1317 - 1382
[6] Efficient and recyclable monomeric and dendritic Ru-based metathesis catalysts
Garber, SB
Kingsbury, JS
Gray, BL
Hoveyda, AH
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (34) : 8168 - 8179
[7] Synthesis and metathesis reactions of a phosphine-free dihydroimidazole carbene ruthenium complex
Gessler, S
Randl, S
Blechert, S
[J]. TETRAHEDRON LETTERS, 2000, 41 (51) : 9973 - 9976
[8] Ivin K. J., 1996, OLEFIN METATHESIS ME
[9] CATALYTIC RING CLOSING METATHESIS OF DIENYNES - CONSTRUCTION OF FUSED BICYCLIC RINGS
KIM, SH
BOWDEN, N
GRUBBS, RH
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (23) : 10801 - 10802
[10] Novel 1,3-diene synthesis from alkyne and ethylene by ruthenium-catalyzed enyne metathesis
Kinoshita, A
Sakakibara, N
Mori, M
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1997, 119 (50) : 12388 - 12389

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