Catalytic upgrading of tri-glycerides and fatty acids to transport biofuels

被引:102
作者
Smith, Benjamin [1 ]
Greenwell, Hugh Christopher [1 ]
Whiting, Andrew [1 ]
机构
[1] Dept Chem, Durham DH1 3LE, England
基金
英国工程与自然科学研究理事会;
关键词
BIODIESEL PRODUCTION; VEGETABLE-OILS; STEARIC-ACID; DIESEL FUEL; SOYBEAN OIL; PALM OIL; HIGHER ALCOHOLS; BASE CATALYST; TRANSESTERIFICATION; DEOXYGENATION;
D O I
10.1039/b814123a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Fuels derived from the lipid fraction of biomass have recently received much attention for carbon neutral substitution of fossil fuels for transport use. In this article we review the current routes to catalytic upgrading of the biomass derived lipid fractions. The history and motivation for biofuels are discussed, including the link to current market trends amongst fuel prices. The sources of lipids and their chemical composition are considered. We review the current literature detailing the use of transesterification reactions (heterogeneous and homogeneous) which lead to oxygenated "Biodiesel", and also decarboxylation, which leads to deoxygenated "Green Diesel". Traditional methods are covered, as well as more recent novel research aiming to produce commercially viable fuels.
引用
收藏
页码:262 / 271
页数:10
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