Synthesis of copper indium sulfide nanoparticles by solvothermal method

被引:88
作者
Han, Shikui [1 ]
Kong, Mingguang [3 ]
Guo, Ying [1 ]
Wang, Mingtai [1 ,2 ]
机构
[1] Chinese Acad Sci, Inst Plasma Phys, Hefei 230031, Peoples R China
[2] Anhui Inst Architecture & Ind, Dept Mat Sci & Engn, Hefei 230022, Peoples R China
[3] Chinese Acad Sci, Inst Solid State, Hefei 230031, Peoples R China
关键词
Nanoparticles; CuInS2; Chalcopyrite; Solvothermal process; SOLAR-CELLS; CUINS2; ROUTE; DECOMPOSITION; NANOWIRES; NANORODS; GROWTH;
D O I
10.1016/j.matlet.2009.02.032
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Single crystalline CuInS2 particles with a chalcopyrite structure and a size of 7-10 nm were prepared by a convenient solvothermal reaction, and characterized by XRD, XPS, TEM (HR-TEM) and UV-vis absorption spectroscopy. The as-synthesized nanoparticles can be redispersed in organic solvents, which will facilitate the practical application of these nanoparticles under organic-solution conditions. The growth of the CuInS2 is regarded to involve the formation and decomposition of Cu2+-thiourea complexes, the reduction of Cu2+. and a slow supply of In3+ ions in the crystallization solution. (C) 2009 Elsevier B.V. All rights reserved.
引用
收藏
页码:1192 / 1194
页数:3
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