Polynuclear coordination complexes - from dinuclear to nonanuclear and beyond

被引：178

作者：

Thompson, LK ^{[1
]}

机构：

[1] Mem Univ Newfoundland, Dept Chem, St John, NF A1B 3X7, Canada

来源：

COORDINATION CHEMISTRY REVIEWS | 2002年 / 233卷

基金：

加拿大自然科学与工程研究理事会;

关键词：

D O I：

10.1016/S0010-8545(02)00101-7

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Polytopic ligands based on aromatic or open chain diazine and alkoxo-fragments form an ideal focus for the simultaneous coordination of metal centers in contiguous groupings, juxtaposed closely enough that magnetic spin-spin exchange occurs between adjacent pairs of metal ions. Examples of polynuclear complexes M-n (n = 2-9) will be discussed in terms of their structures, and principally their magnetic properties, with a focus on self-assembly reactions. Ligand design elements that lead to predictable cluster and grid structures will be emphasized. Magneto-structural studies and correlations will be highlighted with antiferromagnetic and ferromagnetic examples, in addition to recent studies with high nuclearity grids and clusters. Ferromagnetic grids with high spin ground states present exciting possibilities for applications of these nano-scale molecular systems in, e.g. information storage technology. (C) 2002 Elsevier Science B.V. All rights reserved.

引用

页码：193 / 206

页数：14

共 89 条

[1] Spin density maps in the triplet ground state of [Cu2(t-Bupy)4(N3)2](ClO4)2 (t-bupy = p-tert-butylpyridine):: A polarized neutron diffraction study [J].

Aebersold, MA ;

Gillon, B ;

Plantevin, O ;

Pardi, L ;

Kahn, O ;

Bergerat, P ;

von Seggern, I ;

Tuczek, F ;

Öhrström, L ;

Grand, A ;

Lelièvre-Berna, E .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1998, 120 (21) :5238-5245

[2] CRYSTAL STRUCTURE OF A BINUCLEAR NICKEL(2) COMPLEX OF 1,4-DIHYDRAZINO-PHTHALAZINE [J].

ANDREW, JE ;

BLAKE, AB .

JOURNAL OF THE CHEMICAL SOCIETY A -INORGANIC PHYSICAL THEORETICAL, 1969, (09) :1408-&

[3] SYNTHESIS AND STRUCTURE OF A MIXED-VALENCE TETRAMOLYBDATE CONTAINING A BINUCLEATING DIAZENE LIGAND [J].

ATTANASIO, D ;

FARES, V ;

IMPERATORI, P .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1986, (19) :1476-1477

[4] MAGNETIC PROPERTIES OF POLYNUCLEAR COMPLEXES .I. SUPEREXCHANGE IN SOME BINUCLEAR NICKEL(2) COMPLEXES [J].

BALL, PW ;

BLAKE, AB .

JOURNAL OF THE CHEMICAL SOCIETY A -INORGANIC PHYSICAL THEORETICAL, 1969, (09) :1415-&

[5] MAGNETIC-PROPERTIES OF POLYNUCLEAR COMPLEXES .2. SUPEREXCHANGE IN SOME BINUCLEAR COBALT(II) COMPLEXES [J].

BALL, PW ;

BLAKE, AB .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1974, (08) :852-859

[6]

BAXTER PNW, 1994, ANGEW CHEM INT EDIT, V33, P2284, DOI 10.1002/anie.199422841

[7] THE SYNTHESIS, STRUCTURE AND MAGNETIC-PROPERTIES OF A CYCLIC DODECANUCLEAR NICKEL-COMPLEX [J].

BLAKE, AJ ;

GRANT, CM ;

PARSONS, S ;

RAWSON, JM ;

WINPENNY, REP .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1994, (20) :2363-2364

[8] Synthesis, structural characterisation and preliminary magnetic studies of a tetraicosanuclear cobalt coordination complex [J].

Brechin, EK ;

Harris, SG ;

Harrison, A ;

Parsons, S ;

Whittaker, AG ;

Winpenny, REP .

CHEMICAL COMMUNICATIONS, 1997, (07) :653-654

[9] Uncapped and polar capped prisms of cobalt and nickel [J].

Brechin, EK ;

Parsons, S ;

Winpenny, REP .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1996, (18) :3745-3746

[10] Overcrowding leads to prism reform: new polyhedra for polymetallic cages [J].

Brechin, EK ;

Graham, A ;

Harris, SG ;

Parsons, S ;

Winpenny, REP .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1997, (19) :3405-3406

← 1 2 3 4 5 6 7 8 9 →