Citrate selectivity of poly(neutral red) electropolymerized films

被引:46
作者
Broncová, G [1 ]
Shishkanova, TV [1 ]
Matejka, P [1 ]
Volf, R [1 ]
Král, V [1 ]
机构
[1] Inst Chem Technol, Dept Analyt Chem, CR-16628 Prague 6, Czech Republic
关键词
neutral red; electropolymerization; characterization; potentiometric sensor; citrate;
D O I
10.1016/j.aca.2004.01.052
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
The synthesis and the spectroscopic and potentiometric characterization of electropolymerized films obtained from neutral red (NR) on Pt surface are described. FT Raman and H-1 NMR spectroscopy were used for evaluation of the resulting poly(NR) layers. Then potentiometry was applied to study the characteristics of the complexation of carboxylates with the poly(NR) films. A potentiometric poly(NR) sensor showing high selectivity for citrate anion was employed for its determination in soft drinks. (C) 2004 Elsevier B.V. All rights reserved.
引用
收藏
页码:197 / 205
页数:9
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